Big Picture — Classifying and Separating

Mixtures: Classify, then Separate
A mixture
Classify it
Solution, suspension or colloid.
Pick a method
Use a property like size, density, solubility or boiling point.
Pure substances

Which Method Suits Which Mixture?

How do we separate mixtures?
Separation Method fits the mixture
1. Homogeneous mixtures
Parts are dissolved
Example: Crystallization Distillation Chromatography
2. Heterogeneous mixtures
Parts stay separate
Example: Separating funnel Sublimation Centrifugation

Mind Map of the Chapter

Classifying mixtures
Homogeneous or heterogeneous; solutions, suspensions or colloids.
Concentration
Expressed as % m/m, % m/v or % v/v.
Crystallization
Gets a pure solid from its saturated solution.
Distillation
Separates miscible liquids differing by 25 °C or more.
Chromatography
Separates by different rates of movement on paper.
Separating funnel
Separates immiscible liquids by density.
Sublimation
Solid to vapour without melting; deposition is the reverse.
Centrifugation & coagulation
Spin or clump particles to separate them.
Tyndall effect
Colloids and suspensions scatter light.

Key Terms

Solution
A homogeneous mixture, uniform throughout.
Solute / Solvent
The dissolved substance / the dissolving substance.
Concentration
Amount of solute in a given amount of solvent or solution.
Solubility
The most solute that dissolves at a given temperature.
Saturated solution
One that can dissolve no more solute at that temperature.
Crystallization
Forming pure crystals from a saturated solution.
Distillation
Separating miscible liquids by boiling and condensing.
Fractional distillation
Separating liquids with small boiling-point gaps.
Paper chromatography
Separating a mixture by movement on paper.
Immiscible liquids
Liquids that do not mix and form layers.
Sublimation / Deposition
Solid to vapour / vapour to solid, skipping liquid.
Alloy
A homogeneous mixture of metals.
Suspension
A heterogeneous mixture with visible particles.
Centrifugation
Spinning to settle heavier particles.
Coagulation
Clumping fine particles with a coagulant.
Colloid
A mixture between a solution and a suspension.
Tyndall effect
Scattering of light by particles.
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